Penoxsulam (IUPAC: 2-(2,2-difluoroethoxy)-6-(trifluoromethyl)-N-(5,8-dimethoxy[1,2,4]triazolo[1,5-c]pyrimidin-2-yl)-benzenesulfonamide) is a systemic, post-emergence herbicide belonging to the triazolopyrimidine sulfonamide class.
It works by inhibiting acetolactate synthase (ALS/AHAS), an enzyme essential for the biosynthesis of branched-chain amino acids (valine, leucine, and isoleucine). This leads to growth inhibition and eventual death of susceptible weeds.
Mode of Action: ALS inhibitor (HRAC Group B).
Systemicity: Rapidly absorbed by foliage and roots, translocated throughout the plant.
Selectivity: Specifically designed for rice (both transplanted and direct-seeded).
Primary Crop:
Rice (both paddy and direct-seeded systems).
Target Weeds:
Controls a wide spectrum of annual grasses, sedges, and broadleaf weeds, including:
Echinochloa crus-galli (barnyardgrass)
Fimbristylis miliacea (sedge)
Cyperus difformis (smallflower umbrella sedge)
Monochoria vaginalis (pickerelweed)
Ludwigia spp. (water primrose)
Timing:
Applied early post-emergence when weeds are young and actively growing.
Formulation Use:
Available as OD (oil dispersion) or SC (suspension concentrate).
Broad Spectrum: Controls grasses, sedges, and broadleaves with a single application.
Crop Safety: Selective for rice at recommended doses.
Low Use Rate: Effective at very low dosages compared to older herbicides.
Environmental Benefits: Lower application volume reduces chemical load in the field.
Resistance Management Tool: Alternative to ACCase inhibitors and synthetic auxins in rice.
Parameter | Description | Typical Value |
---|---|---|
Chemical Name | Penoxsulam | |
Chemical Class | Triazolopyrimidine sulfonamide | |
Chemical Formula | C₁₆H₁₄F₅N₅O₅S | |
Molecular Weight | ~483.37 g/mol | |
Appearance | Off-white solid | |
Purity (TC) | ≥ 95% | |
Common Formulations | 21.7% OD, 25% SC, 98% TC | |
Mode of Action | ALS inhibitor (systemic) | |
Target Weeds | Grasses, sedges, broadleaf weeds | |
Residual Activity | 2–4 weeks (depending on soil and water conditions) | |
Toxicity | Oral LD₅₀ in rats > 5,000 mg/kg (low mammalian toxicity); slightly toxic to fish & aquatic plants |
Q1: What is Penoxsulam mainly used for?
A: It is primarily used in rice cultivation to control grasses, sedges, and broadleaf weeds.
Q2: How is Penoxsulam applied?
A: Typically applied as a post-emergence foliar spray when weeds are in their early growth stages.
Q3: Does Penoxsulam have residual activity?
A: Yes, it provides 2–4 weeks of residual control, depending on soil type and water management.
Q4: Can Penoxsulam be tank-mixed with other herbicides?
A: Yes, it is often mixed with bispyribac-sodium, pyrazosulfuron-ethyl, or butachlor to broaden the weed control spectrum and manage resistance.
Q5: What is the typical application rate?
A: Generally 15–40 g a.i./ha, depending on crop stage, weed density, and formulation.
Q6: Is Penoxsulam safe for the environment?
A: It is considered environmentally favorable due to low use rates, but caution is advised in aquatic ecosystems.