Oxadiazon: A Pre-Emergence Herbicide for Weed Management

2025-08-22 15:13

Technical Introduction

Oxadiazon is a pre-emergence, contact-type herbicide belonging to the oxadiazole chemical class. It is primarily used to control annual grasses and broadleaf weeds in rice paddies, turfgrass, ornamental crops, and non-crop areas.

  • Mode of Action (MOA): Inhibits protoporphyrinogen oxidase (PPO), an enzyme in chlorophyll and heme biosynthesis. This causes accumulation of toxic intermediates that lead to cell membrane destruction upon light exposure.

  • Characteristics:

    • Acts mainly in the soil layer, preventing weed emergence.

    • Provides long-lasting control due to low solubility and persistence in soil.

    • Limited systemic activity (non-translocated).


Applications

  • Crops:

    • Rice (paddy fields) – widely used for barnyardgrass and sedges.

    • Turfgrass – for weed-free lawns, golf courses, and sod production.

    • Ornamental plants, fruit orchards, vineyards – safe for established plants.

  • Weeds Controlled:

    • Grasses: Echinochloa crus-galli (barnyardgrass), Digitaria spp., Setaria spp.

    • Broadleaves: Amaranthus spp., Chenopodium album, Portulaca oleracea

    • Sedges: Cyperus spp.

  • Application Timing:

    • Applied before weed emergence (0–5 days after transplanting in rice, or pre-sowing in turf/ornamentals).

    • Requires moist soil or irrigation for activation.


Advantages

  • Strong Pre-Emergence Control: Effective against both grasses and broadleaf weeds.

  • Long Residual Effect: Controls weeds for 6–8 weeks.

  • Crop Safety: Well tolerated in rice, turf, and ornamentals.

  • Low Leaching: Minimal movement in soil due to low water solubility, reducing groundwater contamination risk.

  • Resistance Management: Useful in PPO-inhibitor herbicide programs, though rotation is still advised.


Specifications (Typical Parameters)

ParameterDescriptionTypical Value
Common NameOxadiazon
Chemical ClassOxadiazole herbicide (PPO inhibitor)
Chemical FormulaC₁₅H₁₈Cl₂N₂O₃
Molecular Weight~345.2 g/mol
AppearanceBrown crystalline solid
Purity (TC)≥ 95%
Common Formulations95% TC, 50% EC, 25% SC, 2–10% GR
Application Rate0.5 – 1.5 kg a.i./ha (depending on crop)
Mode of ActionPPO inhibition → membrane disruption
Persistence6–8 weeks in soil (low mobility)
ToxicityOral LD₅₀ (rat) > 5,000 mg/kg (very low)

FAQ

Q1: How does Oxadiazon differ from Butachlor or Pretilachlor in rice?
A: Unlike chloroacetamides (Butachlor, Pretilachlor) that inhibit lipid biosynthesis, Oxadiazon acts via PPO inhibition, making it a good rotation partner to delay resistance.

Q2: Can Oxadiazon be used post-emergence?
A: No, it is strictly a pre-emergence herbicide and ineffective once weeds have emerged.

Q3: How long does it protect rice from weeds?
A: Provides 6–8 weeks of weed control, covering the critical early growth stage of rice.

Q4: Is Oxadiazon safe for turfgrass?
A: Yes, it is widely used in lawns, golf courses, and sod farms to maintain weed-free turf.

Q5: Is there a risk of resistance?
A: PPO-inhibitor resistance has been reported in some regions, so rotation with other herbicide classes is recommended.

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