Polyquaternium-22: Versatile Cationic Copolymer for Hair, Skin, and Cleansing Systems

2025-09-02 15:51

Technical Introduction

Polyquaternium-22 is a cationic copolymer made from acrylamide and diallyldimethylammonium chloride (DADMAC). It is amphoteric in nature, meaning it contains both cationic and anionic groups, which makes it compatible across a wide pH range and with various surfactant systems.

  • INCI Name: Polyquaternium-22

  • Chemical Type: Amphoteric copolymer (cationic + anionic functionalities)

  • Appearance: Clear to slightly hazy viscous liquid

  • Charge: Cationic (quaternary ammonium)

  • Solubility: Soluble in water; stable across wide pH ranges

  • Key Function: Film-forming, conditioning, and viscosity enhancement


Applications

1. Hair Care

  • Shampoos & Conditioners → Improves wet & dry combability, softness, and manageability.

  • Styling Products → Provides flexible hold and anti-static effect without build-up.

  • Hair Serums → Enhances shine and reduces frizz.

2. Skin Care

  • Body Washes & Facial Cleansers → Reduces irritation from surfactants, improves skin feel.

  • Creams & Lotions → Film-forming for moisturization and smooth after-feel.

  • Shaving Products → Provides glide and conditioning.

3. Household & Industrial

  • Hand soaps & dishwashing liquids → Improves mildness and after-feel.

  • Fabric care products → Imparts softness and antistatic properties.

  • Surface cleaners → Enhances deposition of active agents.


✅ Advantages

  • Excellent conditioning for both hair and skin.

  • Compatible with anionic, cationic, nonionic, and amphoteric surfactants.

  • Film-forming ability improves long-lasting moisturization and hair protection.

  • Provides anti-static and anti-frizz effects in hair products.

  • Enhances foam stability in cleansing formulations.

  • Stable over a broad pH range (4–12).

  • Non-greasy deposition, prevents buildup.


⚙️ Technical Specifications (Typical Cosmetic Grade)

ParameterSpecification
INCI NamePolyquaternium-22
AppearanceClear to slightly hazy viscous liquid
Solid Content7–12%
Charge DensityCationic (quaternary ammonium)
SolubilityWater-soluble
pH (as supplied)6.0–7.5
Viscosity (Brookfield, 25°C)100–2000 cps (depending on grade)
Recommended Dosage0.5–5.0% (formulation-dependent)
Shelf Life24 months (sealed, cool, dry storage)

⚠️ Safety & Regulatory Notes

  • Globally approved for use in cosmetics and personal care.

  • Non-toxic, non-irritating at recommended concentrations.

  • Considered environmentally safe, though higher concentrations may reduce biodegradability.

  • Widely accepted in EU, USA, and Asia-Pacific markets.


❓ FAQ

Q1: How does Polyquaternium-22 compare to Polyquaternium-10?
PQ-22 is liquid-based and amphoteric, making it more compatible across surfactant systems, while PQ-10 (cationic cellulose) is powder-based and stronger in conditioning.

Q2: Is Polyquaternium-22 suitable for sulfate-free shampoos?
Yes, it is compatible with sulfate-free and mild cleansing systems.

Q3: Does it build up on hair?
No, unlike some cationic polymers, PQ-22 deposits a light, flexible film that rinses easily.

Q4: What is the recommended use level?
Typically 0.5–2% in shampoos and body washes; up to 5% in conditioners or styling products.

Q5: Can it enhance foam in cleansers?
Yes, it stabilizes foam and improves creaminess, especially in body washes.

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