Sodium Hydroxide (NaOH): Essential Alkali for Industrial and Chemical Applications

2025-08-28 17:40

Technical Introduction

Sodium Hydroxide (NaOH), commonly known as caustic soda or lye, is a strong inorganic base widely used in chemical, industrial, and household applications. It is highly alkaline, hygroscopic, and strongly reactive with acids and many organic materials.

  • Chemical Formula: NaOH

  • CAS Number: 1310-73-2

  • Molecular Weight: 39.997 g/mol

  • Appearance: White solid (pellets, flakes, granules) or colorless liquid (aqueous solution)

  • Properties:

    • Highly soluble in water (exothermic dissolution)

    • Strongly alkaline, reacts with CO₂ in air to form sodium carbonate

    • Corrosive to organic tissues and metals in moist conditions


Applications

1. Chemical Industry

  • Raw material for soaps, detergents, and surfactants

  • Used in textile processing, paper pulping, and bleaching

  • Essential in the manufacture of organic and inorganic chemicals (sodium salts, dyes, pharmaceuticals, etc.)

2. Water Treatment

  • pH adjustment in municipal and industrial water treatment

  • Neutralization of acidic wastewater

3. Food Industry (Food-Grade NaOH)

  • Peeling fruits and vegetables

  • Cocoa and chocolate processing

  • Olives curing

  • Production of caramel color and soft drinks (pH control)

4. Pharmaceuticals & Healthcare

  • Production of aspirin, anticoagulants, and other medicines

  • Used as a cleaning and sanitizing agent in medical facilities

5. Household & Cleaning Products

  • Drain cleaners and oven cleaners (dissolves grease and organic matter)

  • Soap and detergent manufacturing

6. Petroleum & Energy Industry

  • Refining petroleum products

  • Used in biodiesel production (transesterification catalyst)


✅ Advantages

  • Strong alkalinity makes it highly effective in neutralization and saponification.

  • Versatile — used across food, chemical, water, and energy industries.

  • Cost-effective large-scale industrial chemical.

  • Readily available worldwide in solid or liquid forms.

  • High solubility in water ensures rapid action in aqueous systems.


⚙️ Technical Specifications (Typical Parameters)

ParameterSpecification (Industrial Grade)
Chemical NameSodium Hydroxide (NaOH)
CAS Number1310-73-2
Molecular Weight39.997 g/mol
AppearanceWhite solid (pellets, flakes, powder)
Solubility in Water~111 g/100 mL at 20 °C (very soluble)
Density (solid)2.13 g/cm³
pH (1% solution)> 13
Melting Point318 °C
Boiling Point1,388 °C
StorageAirtight container, cool and dry place
Purity (industrial grade)95 – 99%
Purity (food/pharma grade)≥ 99%

⚠️ Safety & Regulatory Notes

  • Corrosive: Causes severe burns to skin, eyes, and mucous membranes.

  • Handling Precautions:

    • Use protective gloves, goggles, face shield, and clothing.

    • Store in sealed containers away from acids and moisture.

  • Environmental Impact: Highly alkaline effluents can harm aquatic life if not neutralized.

  • Regulatory Approval:

    • Approved for controlled use in food processing (E524).

    • Strict safety handling required under OSHA, EU REACH, GHS.


❓ FAQ

Q1: What is the difference between caustic soda flakes, pearls, and liquid?
They are all NaOH with the same chemistry; the difference is only the physical form (solid flakes, beads/pearls, or aqueous solution).

Q2: Is sodium hydroxide safe in food?
Yes, food-grade NaOH (high purity) is used under controlled conditions for peeling, curing, or pH adjustment. It is not consumed directly but removed or neutralized.

Q3: Why is NaOH used in soap making?
It reacts with fatty acids in oils/fats in a process called saponification, producing soap and glycerin.

Q4: Can sodium hydroxide dissolve organic matter?
Yes. It breaks down proteins, fats, and greases, which is why it is used in drain cleaners.

Q5: What precautions should be taken when handling NaOH?
Always wear protective equipment, avoid inhalation of dust/fumes, and ensure proper ventilation. If contact occurs, wash immediately with water.

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